One player cannot have chemistry. A team however, can. How about personality types? An aggressive player type would commit more fouls, but will play hard nosed basketball(drive to the rim with no concern of injury, grab boards with ease, etc). An entertainer, like the title states, plays entertaining basketball, and gets along with teammates quite well. He is a fan favorite, and more fans are likely to watch your games if he's a part of it. His flashy moves however, come at a price. Behind the back passes, crazy lobs, and sick crossovers are all part of his game, but turnovers are likely. You get the point, come up with some more.